2020 A/L Physics Past Paper · Question 35 (English Medium)

The largest mass of ice that can melt in 35 °C water

In a container of negligible heat capacity, what is the largest mass of ice at −5∘C-5^\circ\text{C} that can melt completely in 1 kg1\ \text{kg} of water at 35∘C35^\circ\text{C}? Take the specific heat capacities of ice and water as 2.0×103 J kg−1 ∘C−12.0 \times 10^3\ \text{J kg}^{-1}\,{}^\circ\text{C}^{-1} and 4.0×103 J kg−1 ∘C−14.0 \times 10^3\ \text{J kg}^{-1}\,{}^\circ\text{C}^{-1} respectively, and the specific latent heat of fusion of ice as 3.4×105 J kg−13.4 \times 10^5\ \text{J kg}^{-1}. Assume no heat is exchanged with the surroundings.

  1. (1) 200 g200\ \text{g}
  2. (2) 240 g240\ \text{g}
  3. (3) 300 g300\ \text{g}
  4. (4) 360 g360\ \text{g}
  5. (5) 400 g400\ \text{g}
Answer and explanation

Answer: (5) 400 g400\ \text{g}

Given information

Given: water mw=1m_w = 1 kg, 35∘C35^\circ\text{C}, cw=4.0×103 J kg−1 ∘C−1c_w = 4.0 \times 10^3\ \text{J kg}^{-1}\,{}^\circ\text{C}^{-1}; ice at −5∘C-5^\circ\text{C}, ci=2.0×103c_i = 2.0 \times 10^3; l=3.4×105 J kg−1l = 3.4 \times 10^5\ \text{J kg}^{-1}; no heat exchanged with the container or surroundings.

What the question asks

We must find: the largest mass of ice that can melt completely.

Relevant theory

The amount of heat required to raise the temperature of a unit mass of a substance by 1 unit of temperature (1 °C or 1 K) defined as the specific heat capacity of that substance.

Heat removed from the hot object = Heat acquired by the cold object

Thermal energy is absorbed by the solid for this process during the whole period in which this transformation occurs. Even though the thermal energy is absorbed there is no increase in temperature.

Specific latent heat of fusion of a solid material is defined as the heat required to change the state of a unit mass of a solid to liquid without change of temperature (at its melting point).

Required equations

Qw=mwcw(35−0)Q_w = m_w c_w (35 - 0)

Qi=mci(0−(−5))+mlQ_i = m c_i (0 - (-5)) + m l

Qw=QiQ_w = Q_i

Applying it to this question

Plan: while any ice remains, the mixture cannot fall below 0∘C0^\circ\text{C}; so the most heat the water can give is from 35→0∘C35 \to 0^\circ\text{C}.

(1) that heat; (2) the heat needed per kg of ice; (3) divide.

Reasoning and calculation

1.4×1051.4 \times 10^5

Qw=1×4.0×103×35Q_w = 1 \times 4.0 \times 10^3 \times 35

1.0×1041.0 \times 10^4

2.0×103×52.0 \times 10^3 \times 5

3.4×1053.4 \times 10^5

ll

3.5×1053.5 \times 10^5

1.0×104+3.4×1051.0 \times 10^4 + 3.4 \times 10^5

0.400.40

m=1.4×1053.5×105m = \frac{1.4 \times 10^5}{3.5 \times 10^5}

400400

m=0.40×1000m = 0.40 \times 1000

Checks

Unit check: kg×J kg−1 ∘C−1×∘C=J\text{kg} \times \text{J kg}^{-1}\,{}^\circ\text{C}^{-1} \times {}^\circ\text{C} = \text{J}; JJ kg−1=kg\dfrac{\text{J}}{\text{J kg}^{-1}} = \text{kg} ✓.

Physical plausibility: most of the heat goes into melting (only 1.0×1041.0 \times 10^4 of 3.5×1053.5 \times 10^5 J warms the ice up to 0∘C0^\circ\text{C}); 11 kg of water at 35∘C35^\circ\text{C} melting 400400 g of ice is reasonable ✓.

mw∗cw∗th0/(ci∗5+L)∗1000mw * cw * th0 / (ci * 5 + L) * 1000

Conclusion

m=1.4×1053.5×105=0.40 kgm = \frac{1.4 \times 10^5}{3.5 \times 10^5} = 0.40\ \text{kg}

The water gives 1.4×1051.4 \times 10^5 J down to 0∘C0^\circ\text{C}; each kg of ice needs 3.5×1053.5 \times 10^5 J, melting 0.400.40 kg — the answer is (5) 400400 g.

Forgetting the heat needed to warm the ice from −5∘C-5^\circ\text{C} to 0∘C0^\circ\text{C}.

Before it can melt, the ice must first reach 0∘C0^\circ\text{C}: add mci×5m c_i \times 5 as well.

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